Ti-V-Cr阻燃合金的吸氢动力学.pdf

RareMetalMaterialsand Availableonlineat Engineering Volume 2011 ●一#∥ 40，Issue 9，September Online editionoftheChinese English languagejournal Kineticsof inTi-V-CrBu nt HydrogenAbsorption Alloy Zhao Xiaolill2， Wang Honglian93， Weidon91 Yongqin92，WangYaoqi3，Hou Zeng ’Northwestern NorthwestInstituteforNon-FerrousMeal PolytechnicalUniversity,,Xran710072,Chma；2 Research。Xian710016,Chma；3 Aeronautical Research 100024。china BeUing ManufacturingTechnologyInstitute。Beijing Abstract：The kineticsofTi40 wasstudiedinthe of550-700oCandthe of hydrogenabsorption alloy temperaturerange pressurerange 15．88-45．88kPa．Theinitial of forTi40 is515oC．Withtheincreaseof andinitial temperaturehydrogenabsorptionalloy temperature to timereachthe conditionbecomes rateand hydrogenpressure，the equilibrium shorter。whilehydrogenabSorptionequilibriumhydrogen increase．Atlow consistsofthree incubationthefirst pressure temperature。theprocessofhydrogenabsorption stages：I stage。II absorption andⅢthesecond thesame rateconstantsatdifferentfollowthe stage absorptionstage．At temperature，the stages relation：七Ⅱ七I七Ⅲ．At thesanle rateconstantsincreasewiththeincrease activationofthefirstandsecond are stage．the oftemperature．Theenergy