胺化聚苯乙烯树脂的制备及吸附对硝基酚.pdfVIP

化 工 进 展 ·1714 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2015 年第 34 卷第 6 期 研究开发 胺化聚苯乙烯树脂的制备及吸附对硝基酚 孟启，舒斌斌，周峰，夏丰敏，孙小强 （常州大学石油化工学院，江苏常州 213164 ） 摘要：以氯甲基化聚苯乙烯树脂（PS-Cl ）和氯乙酰化聚苯乙烯树脂 （PS-Acyl-Cl ）为母体，引入三乙烯四胺（TETA） 制备两种胺化聚苯乙烯树脂 PS-TETA 与 PS-Acyl-TETA 。用红外光谱和表面孔径吸附仪对树脂进行表征，并用 于对硝基酚（PNP ）的吸附研究。静态和动态吸附实验结果表明，两种树脂对 PNP 的吸附过程都可以用准二级 动力学方程来描述；液膜扩散为吸附 PNP 的主要控制步骤；吸附符合 Freundlich 等温方程，为多分子层吸附； 吸附为自发的放热过程，属于以物理吸附为主的吸附过程；PS-TETA 与 PS-Acyl-TETA 对 PNP 的饱和吸附量分 别为 157.87mg/mL、90.77mg/mL ，穿透体积为 165BV、80BV，动态脱附率为 98.4% 、98.9% 。 关键词：三乙烯四胺; 树脂; 吸附; 对硝基酚 中图分类号：O 632.6 文献标志码：A 文章编号：1000 –6613 （2015 ）06 –1714 –06 DOI ：10.16085/j.issn.1000-6613.2015.06.033 Preparation of aminated polystyrene resins and its adsorption of p -nitrophenol MENG Qi ，SHU Binbin ，ZHOU Feng ，XIA Fengmin ，SUN Xiaoqiang （School of Petrochemical Engineering，Changzhou University，Changzhou 213164，Jiangsu，China ） Abstract ：Two kinds of aminated polystyrene resins，PS-TETA and PS-Acyl-TETA were prepared with triethylenetetramine (TETA) by reacting with chloromethyl polystyrene resin (PS-Cl) and chloroacetylated polystyrene resin (PS-Acyl-TETA) ，respectively. The structure of resins was charactered with FTIR and BET ，and the adsorptions of p -nitrophenol (PNP) were investigated. The static and dynamic adsorption experimental results show that the adsorption processes for the PNP of two resins can be described by pseudo-second order kinetic equation. The main control steps of two kinds of resins adsorption PNP are governed by liquid film diffusion. The adsorption data of PNP on two kinds of resins are fitted into Freundlich isotherms ，which belong t