醇-水基料浆凝胶注模成形制备氧化铝多孔陶瓷.pdf

第19 卷第1 期 粉末冶金材料科学与工程 2014 年2 月 Vol.19 No. 1 Materials Science and Engineering of Powder Metallurgy Feb. 2014 醇−水基料浆凝胶注模成形制备氧化铝多孔陶瓷 彭 俊，李国栋，熊 翔，刘靖忠，霍凌霞 ( 中南大学 粉末冶金国家重点实验室，长沙 410083) 摘 要：以氧化铝粉为原料，乙醇–水为溶剂，采用凝胶注模成形工艺制备氧化铝多孔陶瓷，并研究溶剂中醇、 水体积比对多孔陶瓷坯体和烧结体的收缩率、孔隙度、微观形貌及性能的影响。结果表明：多孔陶瓷的孔隙由溶 剂挥发形成的 “溶剂孔”和高聚物分解形成的 “高聚物孔”两部分组成，孔隙呈三维贯通孔结构。当醇、水体积 比由3:7 增加至9:1 时，制品线收缩率与抗弯强度逐渐减小，孔隙度和气体渗透通量逐渐增加。当醇、水体积比 为7:3 时，所制备的陶瓷具有优良的综合性能：孔隙率为76.91%，孔隙分布均匀，抗弯强度为13.08 MPa ，气体 3 2 渗透通量达到135.6 m /(m ·h ·kPa) 。 关键词：凝胶注模；氧化铝；醇水比；多孔陶瓷 中图分类号：TQ174 文献标识码：A 文章编号：1673-0224(20 14)1-47-07 Porous alumina ceramics prepared by alcohol-water based gel casting process PENG Jun, LI Guo-dong, XIONG Xiang, LIU Jing-zhong, HUO Ling-xia (State Key Laboratory of Powder Metallurgy, Central South University, Changsha 410083, China) Abstract: Using high purity alumina powder as raw material, alcohol-water mixture as solvent, porous alumina ceramics were fabricated by alcohol-water based gel casting process. The effect of alcohol-water solvent ratio on the shrinking percentage, porosity, microstructure, properties of porous alumina green body and sintered ceramics were investigated. Both evaporation of solvent and decomposition of polymer contribute to the porous microstructure of the as-prepared green body and sintered ceramics, which features three dimensional inter-connected pores. With increasing the alcohol-water ratio from 3:7 to 9:1, the line shrinking percentage and flexural strength decrease, porosity and