太阳能级多晶硅定向凝固技术的研究进展.pdf

Vol.29 No. 5 ay 2008 FOUNDRY TECHNOLOGY 673 Todays Foundry 武冠男, 张 军,刘 林,傅恒志 (, 710072) : 随着太阳能光伏产业在全球范围内的迅猛发展, 作为太阳能电池最基础的原材料 高 多晶硅, 在全球范围内严重 短缺, 迫切需要发展一种高效率低成本的太阳能级多晶硅的制备方法在各种生产多晶硅的方法中, 定向凝固多晶硅因其成 本低环境污染小,工艺相对简单成熟,且能直接使用冶金级硅为原料的特点,被寄予很大的希望来实现大规模太阳能级硅 的生产本文综合评述近年来太阳能级多晶硅定向凝固技术的研究进展,着重阐述冶金级硅中磷和硼的提 , 以及多晶硅定 向凝固组织和缺陷的控制, 并提出今后的研究发展方向 : 太阳能级多晶硅; 定向凝固; 提 + :TG244 .3 :A :2008 Research Progress of Direct ional Solidif icat ion Technology f or Solar Grade Mult icrystalline Silicon WU Guannan, ZHANG Jun, LIU Lin, FU Hengzhi ( State Key Labo ato y of Solidification P ocessing, No thweste n Polytechnical Unive sity, Xian 710072, China) Abstract: With the rapid development of photovoltaic industry in the world, highpurity multicrystallinesiliconwhichisthe basic material for solarcell is insevereshortage. Subsequently, it is imperious to developa new preparation methodfor solar gradesiliconwith highefficiency and low cost. Among the various approaches of producing multicrystalline silicon, directional solidificationtechnology is regarded as a prospective way to realize the largescale production for solargradesilicon due to low cost, less environment pollution, comparatively mature and simple technology, and using metallurgical grade silicon as raw material. In this paper, the worldwide researchprogress of directional solidification technology for solar grade multicrystalline silicon is reviewed. The purification technique for phosphorus and boron in metallurgical grade silicon is introduced indetails. oreover, thedirectionallysolidified microstructureand defect controlarealso presented. Finally thefuturedevelopment directionsof directional solidificationtechnology for solar grade multicrystallinesiliconare proposed. Key w