粉煤灰水热合成A沸石及其生长机理研究.pdf

30 2 武 汉 理 工 大 学 学 报 Vol. 30 No. 2 2008 2 JOURNAL OF WUHAN UNIVERSITY OF TECHNOLOGY Feb. 2008 A 1,2 3 2 2 付克明 , 刘桃香 , 张勤善 , 原东林 ( 1. , 100083; 2. , 454100; 3., 430070) : 通过对粉煤灰水热制备A 型沸石实验和晶体生长过程的研究, 发现了A 型沸石新的生长过程, 并由此 出了 新的水热法合成A 型沸石的生长机理实验证明,粉煤灰煅烧特别是加碱煅烧能 高其反应活性,并揭示了水热体系中 A 型沸石的生长经历了粉煤灰颗粒的溶解y Al(OH) 沉淀y Al(OH) 沉淀溶解y 硅铝酸盐凝胶y 集聚y 初晶( 晶核) y 3 3 完整晶体等阶段硅铝酸盐凝胶的集聚是形成晶核的基础, 晶核及小颗粒的集聚则是A 型沸石晶粒长大的主要方式 : 粉煤灰; 预处理; A 型沸石; 水热合成; Al( OH) 沉淀; 集聚生长 3 : O 781 : A : 1671-4431(2008)02-0025-03 Hydrothermal Synthesis o Zeolite A rom Fly Ash and Its Growth Mechanism 1, 2 3 2 2 F U K e- ming , L I U Tao-x iang , ZHA N G Qi n-shan , Y UA N Dong-li n ( 1. School of Che ical and Environ ental Engineering, China University of Mining Technology, Beijing 100083, China; 2. School of Che ical and Environ ental Engineering, Jiaozuo University,Jiaozuo 454100,China; 3.School of Materials Science and Engineering, Wuhan University of Technology, Wuhan 430070, China) Abstract: The synthetical experi ents of zeolite A fro fly ash and the crystal growth process were investigated in the hy- drother al syste , a new growth process of zeolite A has been found, hencethe new growth echanis of hydrother al syn- thesis of zeoliteA fro fly ash was prop