克拉玛依减渣及其临氢热反应产物中钙化合物的分布与存在形态_邓文安.pdfVIP

() 2007 6 　 　　　　 　　ACTA PETRO LEI SINICA (PETRO LE UM P ROCESSING SECTION)　 　　 　　　23 3 　 :100-1 8719(2007)03-008-0 07 THE DISTRIBUTION AND CONFIGRATION OF CALIUM COMPOUNDS IN THE KARAMARY VACUUM RESIDUE AND ITSTHERMAL REACTION PRODUCTSUNDER DISPERSED CATALYST AND HYDROGEN ATMOSPHERE 邓文安, 马莉莉, 阙国和 DENG Wen-an, MA L-i li, QU E G o-he ( , 257061) (S tat e K ey L aborat ory of H eavy Oi l P rocessi ng , China Uni versi ty of P et roleum, D ong y ing 257061, Chi na) :(KLVR) 。 FT-IR、 GC-MS、 XPS、 XRD KLVR 。 , KLVR , ; , , , 。 KLVR , 。 　　:;;;; :TE624. 3 　　:A Abstract:T he distrib tions of calci m compo nds w ere st died in Karamary vac m resid e (KLVR)and its thermal reaction prod cts nder dispersed catalyst and hydrogen by the method of solvent extraction. T he config ration of calci m compo nd w as investigated by FT-IR, GC-MS, XPS and XRD. The res lts show ed that most of the calci m compo nds existed in acetone insol ble and n-pentane asphaltene of K LV R, and few w as in the acetone sol ble. T he calci m contents in the acetone insol ble and n-pentane asphaltene were grad ally decreasing, w hile the calci m content in the tol ene insol ble w as increasing w ith the increasing of reaction severity nder dispersed catalyst and hydrogen atmosphere. The calci m w as combined with petrole m acid in KLV R and its thermal reaction vac m bottom oil, and the calci m compo nd in the tol ene insol ble of thermal prod cts w as calci m s lfate after the tol ene insol ble w as transfered to ashes at low temperat re. Key wor s:Karamary vac m resid e;calci m compo nd;thermal reaction nder hydrogen atmosphere;distrib tion;config ration 　　, , , [1] , 、 。, 9