《Highly dispersed iron species created on alkalitreated zeolite for ammonia SCR》.pdfVIP

Progress in Natural Science: Materials International 2013;23(5):493–500 Chinese Materials Research Society Progress in Natural Science: Materials International /locate/pnsmi ORIGINAL RESEARCH Highly dispersed iron species created on alkali-treated zeolite for ammonia SCR a a,b,n a,c b a Jing Ma , Duan Weng , Xiaodong Wu , Zhichun Si , Zhenwei Wu aState Key Laboratory of New Ceramics Fine Processing, School of Materials Science and Engineering, Tsinghua University, Beijing 100084, China bAdvanced materials institute, Graduate School at Shenzhen, Tsinghua University, Shenzhen 518055, China cYangtze Delta Region Institute of Tsinghua University, Zhejiang 314000, China Received 19 March 2013; accepted 22 June 2013 Available online 19 October 2013 KEYWORDS Abstract Alkaline treatment using sodium hydroxide was introduced to obtain a hierarchical pore structure in H–ZSM-5 zeolite. Fe-exchanged zeolite catalysts were prepared by impregnation on the Fe/ZSM-5; original and alkali-treated zeolites, and were evaluated for NO reduction by NH , NO oxidation, and NH Alkaline treatment; x 3 3 Brønsted acidity; oxidation reactions. The highly dispersed iron species as active sites can be obtained by controlling the Iron dispersion;