《Hydrogenation of Commercial Polystyrene over PdBaSO4 CatalystsEffect of Carrier Structure》.pdfVIP

Trans. Tianjin Univ. 2014, 20: 282-291 DOI 10.1007/s12209-014-2363-y Hydrogenation of Commercial Polystyrene over Pd/BaSO4 Catalysts: Effect of Carrier Structure * Han Kaiyue (韩凯悦), Meng Chen (孟 晨), Zhu Zhenwei (朱振炜), Cao Guiping (曹贵平) (UNILAB, State Key Laboratory of Chemical Engineering, School of Chemical Engineering, East China University of Science and Technology, Shanghai 200237, China) © Tianjin University and Springer Verlag Berlin Heidelberg 2014 Abstract ：A variety of barium sulfate (BaSO4) carriers with or without mesopore structure were synthesized via precipitation reaction in aqueous solution of barium hydroxide and sulfuric acid with ethylene glycol as a modifying agent, and then calcined at various temperatures. The obtained BaSO4 was used as catalyst carriers for polystyrene (PS) hydrogenation, and BaSO4 supported palladium (Pd) catalysts with Pd content of 5wt% were prepared by using impregnation method. N2 physisorption, transmission electron microscopy, X-ray diffraction and kinetics studies were used to investigate the effect of carrier structure on the dispersion and geometric location of active metal and their catalytic activities in PS hydrogenation. It was found that the pore structure of carrier played an important role in the dispersion and location of Pd grains. The activation energy values for all the Pd/BaSO4 catalysts were around 49.1 kJ/mol, while the pre-exponential factor for Pd/BSC-6H was much higher than others. The Pd/BSC-6H without mesopores had Pd grains deposited on the external surface of the carrier, and exhibited better activity