内蒙古河套平原高砷地下水中稀土元素含量及分异特征.pdfVIP

第 l7卷 第 6期 地学前缘 (中国地质大学 (北京)；北京大学) V0I_l7No．6 2010年 ¨月 EarthScienceFrontiers(ChinaUniversityofGeosciences(Beijing)；PekingUniversity) NOV．2010 内蒙古河套平原高砷地下水 中稀土元素含量及分异 特征 郭华明， 张 波，李 媛，魏 亮， 张 扬 中国地质大学(Jr京)水资源与环境学院，北京 100083 GuoHuaming， Zhang13o， LiYuan， WeiLiang， ZhangYang SchoolofWaterResourcesandEnvironment，ChinaUniversityofGeosciences(Beijing)，Beijing100083，China GuoHuam ing，ZhangBo，LiYuan，eta1．Concentrationsandpatternsofrareearthelementsinhigharsenicgroundwatersfrom theHetaoPlain，InnerMongolia．EarthScienceFrontiers，2010，17(6)：059-066 Abstract：High arsenicgroundwaterisaworld—wideenvironmentalissue．Although theprogresshasbeen madeconcerning thegeochemistry，formationenvironmentandAsenrichmentmechanism ofhigh Asgroundwa- ters，theconcentrationsandpatternsofrareearthelement(REE)inthesegroundwatersareunclear．Ground— watersamplesfrom theHetaoBasin，atypicalhighAsgroundwaterbasininChina，areinvestigatedthrough in-situmeasurementsandlaboratoryanalyses．W efoundthattheconcentrationofREE isrelativelylow inthe highAsgroundwatersamples．ThedatanormalizedaccordingtoNorthernAmericanShaleComposite(NASC) exhibitaREEpatternwithenrichedHREEsanddepletedLREEsforallgroundwatersamples．HREEsenrich— mentcanbeexplainedby carbonatecomplexation，whilereadsorption in slightlyweakalkalineenvironment couldbethecauseofLREEsdepletion．Allgroundwatersamplesshow positiveEuanomalies，whilemostof them show negativeCeanomalies．ThepositiveEuanomaliesseem tOhaveresultedfrom reductivedissolution ofFeoxyhydroxidesand／orreductivedesorption．ArsenicconcentrationsincreasewithincreasingEEu]NAS【． Generallyspeaking，positiveEuanomalieswouldreflectAsenrichmentinreducinggroundwaterenvironments． Keywords：hydrogeochemistry；REE；enrichment；fractionation；redoxcondition 摘 要：高砷地下水是世界范围内的一个重大环境 问题。尽管已有工作在高砷地下水的地球化学特征、形成 条件和富砷机理等方面取得了很大进展，但其稀土元素 (REE)含量及