《Hydrothermal Synthesis Structure Characterization and Magnetic Studies of Perovskitetype Fluorides K2NaVF6 and NH4aVF6》.pdfVIP
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CHEM.RES.CHINESEUNWERSITlES
2012,28(3),37卜一374
Characterizationand
HydrothermalSynthesis,Structure Magnetic
of Fluorides
Studies K2NaVF6
Perovskite—type
HE andZOUB02
Dongp,FENGShou-hua3,CHEN
Li-jiel,ZHANG Gan92
115000.P尼China;
,.CollegeoJChemistry,HngkouUniversityZone,Hngkou
2,State
KeyLaboratoryofSuperhardMaterials.College
ofPhysics。
3.State and
KeyLaboratoryofInorganicSynthesisPreparativeChemistry,CollegeofChemistry,
Jilin 130012.P尼China
University,Changchun
AbstractTwo fluorides were undermild con-
perovskite-typeK2NaVF6and(NH4)3VF6synthesizedhydrothermal
were
ditions.Thestructuresofthe determinedmeansof diffraction Riet-
compounds by powderX-ray analysis.The
hasa and
veldrefinementindicatesthat cubic structure in Fm3m
K2NaVF6 elpasolite-type crystallizesspacegroup
withlatticeconstantl has in
a28.3 acubic structureand
80(21nm.fNH4)3VF6cryolite—type crystallizesspacegroup
F
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