Li1.2Ni0.13Co0.13Mn0.54O2正极材料的制备及性能.pdf

赵桢，叶学海。郅晓科，何爱珍，王旭阳 (中海油天津化工研究设计院，天津300131) C首次放电比 材料进行了表征。结果表明。所合成的材料具有球形形貌。粒度分布均匀，振实密度达2．1．g／cma，材料0．2 容量280．9 C首次放电比容量237．1 C容量保持率92．5％，表现出优异的电化学性能。 mAh／g，1 mAh／g．循环50次后1 关键词：锂离子电池；正极材料；Lil2Ninl3c001州nn斟02；循环伏安；交流阻抗 912．9 中图分类号：TM 文献标识码：A 文章编号：1002—087 X(2014)07—1221—03 andcharacteristicsof cathodematerials Synthesis Lil．2Ni叭3Coo．13Mno．5402 ZHAO Zhen，YEXue-hi，ZHIXiao-ke，HEAi—zhen，WANGXu-yang Chemical (cNoocTianjm 300131．China) Research＆D璐|留／nst／tute,Tianjm Abstract：Thecathodematerial was a carbonate Lil州i0．13C0013Mn05402synthesizedusingnickel-cobalt—manganese withlithium。The obtainedchemical precursor sphereprecursorNinl3C0011州no．54(0H)憾wasby co-precipitation method．The werecharacterizedX diffraction electron U”Ninl3c0013Mnn5402powders by ray (XRD)。scanning microscopy(SEM)，cyclicvoltammetry(cv)，electrochemicalimpedance and tests．Theresultsshowthat exhibit anduniform galvanostaticcharge_clischarge padiclesspherical morphology size．The ofmaterialis to2．1 initial of is particle tap-density g／cm3．The up dischargecapacityLil2Ninl3C001州no5402 280．9 at0．2 isobtainedat1 Candthe retentionis 50 at1 C，237．1