MnMg共掺杂对锂离子电池正极材料的影响.pdf

Journal of The Electrochemical Society, 157 9 A993-A1001 2010 A993 0013-4651/2010/1579/A993/9/$28.00 © The Electrochemical Society Synthesis, Characterization, and Thermal Stability of LiCo1−z †MnMg‡zÕ 2O2 Wenbin Luo,a,b,* Xinhai Li,b and J. R. Dahna,**,z aDepartment of Physics and Atmospheric Science, Dalhousie University, Halifax B3H3J5, Canada b School of Metallurgical Science and Engineering, Central South University, Changsha 410083, People’s Republic of China LiCo1−z MnMgz/2O2 0 z 0.7 samples were prepared from Co1−z MgMnz/2 OH2 precursors. The hydroxide precursors were heated with Li2CO3 at 900°C for 3 h to prepare the oxides. Electrochemical studies of the LiCo1−z MnMgz/2O2 0 z 0.3 samples were used to measure the rate of capacity reduction with Mn + Mg content, found to be about −130 mAh/g/ z = 1. The results of in situ X-ray diffraction and differential capacity measurements show that irreversible loss of oxygen, along with lithium extraction, from the compound with z = 0.3 occurs during the first charge between 4.4 and 4.6 V. The impact of Mn and Mg cosubstitution on the thermal stability of LiCo1−z MnMgz/2O2 samples was studied via accelerating rate calorimetry. There is little or no improvement in thermal stability caused by Mn and Mg cosubstitution. © 2010 The Electrochemical Society. DOI: 10.1149/1.3457425 All rights res