聚吡咯氧化石墨烯层状复合材料的制备及其在超级电容器中的应用英文.pdfVIP

18 4 电化学 Vol． 18 No． 4 第 卷 第 期 2012 8 JOURNAL OF ELECTROCHEMISTRY Aug． 2012 年 月 Artical ID :1006-347 1 (2012)04-0348-11 Electrochemical Performances of Layered Polypyrrole / Chemically Reduced Graphene Oxide Nanocomposites as Supercapacitor Electrodes * XU Si-zhe ，ZHOU Xue-jiao ，WU Kun ，YANG Yong -qiang ，WU Hai-xia (Research Institute of M icro / Nano Science and Technology ，Shanghai Jiao Tong Univers ity ， Shanghai 200240 ，China) Abstract : Nanocomposites of polypyrrole (Ppy )and chemically reduced graphene oxide (CRGO )，Ppy / CRGO ，have been fabricated through in-s itu polymerization of pyrrole on graphene oxide (GO )sheets． The as- synthesized Ppy / CRGO composites w ere characterized complementarily using scanning electron microscopy (SEM )，thermogravimetric analysis (T GA )and Fourier transformed infrared spectroscopy (FT -IR)． By control- ling the initial ratio of the GO to pyrrole ，the layered composites could be obtained and their thickness could be tuned properly ． The Ppy / CRGO electrodes w ere prepared using a mechanical compressing technique and their elec- trical conductivity and electrochemical properties w ere characterized systematically ． We demonstrated that as elec- trodes for supercapacitor ，the Ppy / CRGO composites w ith Ppy to CRGO mass ratio of 10 ∶1 show ed a competitive