新型含磷阻燃剂的制备及性能.pdfVIP

化 工 进 展 ·2140 · CHEMICAL INDUSTRY AND ENGINEERING PROGRESS 2014 年第33 卷第8 期 研究开发 新型含磷阻燃剂的制备及性能 蒋巍，姚姗姗 （吉林化工学院材料科学与工程学院，吉林吉林 132022 ） 摘要：以双三羟甲基丙烷为原料合成一种新型含磷阻燃剂，该阻燃剂分子量较大，具有稳定的环状结构，热稳 定性高于常用阻燃剂，阻燃效果好。探讨了原料配比、反应温度、反应时间对产率的影响，考察了目标产物的 热稳定性能及其对不同织物的阻燃效果，用傅里叶变换红外光谱仪表征了中间体及目标产物的结构。结果表明， 当原料配比为 1 ∶3 时，磷化温度为 50℃，磷化时间5h，胺化温度为75℃时，反应效果较好，收率可达 90% 以上。目标产物对于锦纶的阻燃效果比较明显，对涤纶、棉有一定的阻燃效果，对于混纺、腈纶阻燃效果不 明显。 关键词：双三羟甲基丙烷；乙醇胺；阻燃剂；性能 中图分类号：O 632.52 文献标志码：A 文章编号： 1000 –6613 （2014 ）08 –2140 –05 DOI ：10.3969/j.issn.1000-6613.2014.08.033 Preparation and flame retardancy of a novel phosphorous-containing flame retardant JIANG Wei ，YAO Shanshan （College of Materials Science and Engineering，Jilin Institute of Chemical Technology ，Jilin 132022 ，Jilin ，China ） Abstract ：A novel phosphorous-containing flame retardant was synthesized with double trimethylolpropane as raw material. The flame retardancy of the flame retardant is good due to its high molecular weight ，stable loop structure ，and higher thermal stability compared with common flame retardants. The effects of raw material ratio ，reaction temperature and reaction time on the yield were discussed. The thermal stability of target product and its flame retardancy to different fabrics were investigated. The structures of intermediates and target product were characterized with Fourier transform infrared spectrometer. The results show that reaction effect was better when raw material ratio was 1 ∶3，phosphating temperature was 50 ℃，reaction time was 5h ，and amination temperature was 75 ℃. And the flam