Al13柱撑膨润土的制备及柱化影响因素的研究.pdf

第 卷第 期 33 4 Vol.33 No.4 非金属矿 2010 年 7 月 Non-Metallic Mines July, 2010 Al13柱撑膨润土的制备及柱化影响因素的研究 郑举功  杨 婷  刘晓东  陈泉水 （东华理工大学材料科学与工程系，江西 抚州 344000） 摘  要 以钠化改型后的内蒙古高庙子膨润土为原料，Al13 高聚体为柱化剂，采用水热离子交换法，合成了Al13 高聚体柱撑膨润土(Al13 pillared Clay, Al13-PILC)。通过X- 射线粉晶衍射(XRD) ，扫描电镜(SEM) 分析了产物的结构和形貌，探讨了制备Al13-PILC 的工艺参数对结构的影响。 结果表明，钠化后的膨润土呈现大而薄的颗粒，铝柱撑膨润土颗粒仍保留了较完整的层状和片状结构；铝柱撑剂撑开的d(001) 层间距可达1.889 nm ； 最佳工艺参数为：铝/ 土比10 mmol/g，水热反应温度90 ℃，柱撑老化时间72 h。 关键词 高庙子 膨润土 铝柱撑剂 水热离子交换法 Al13 柱撑膨润土 TD97 A 1000-8098(2010)04-0009-04 中图分类号： 文献标识码： 文章编号： Preparation of Al-pillared Clay and Study of Pillaring Influencing Factor Zheng Jugong Yang Ting Liu Xiaodong Chen Quanshui ( Department of Material Science and Engineering, East China Technology University, Fuzhou, Jiangxi 344000 ) （ ） Abstract Al13 pillared Clay Al13-PILC was prepared by hydro-thermal ino-exchage methods with Caomiaozi (GMZ) bentonites as raw material which was purified and sodium-modified and Al13 as pillaring agent. Structure and morphology of the sample was described by X-ray powder diffraction (XRD), scanning electron microscopy (SEM). The results show Na-bentonite presents large and thin particles. Al-PILC retains more complete layered and sheeting structure . The interlayer spacing d(001) is up to 1.889 nm. The optimal synthesis parameters are as follows: a ratio of Al/ bentonite of 10 mmol/g, hydrothermal reaction at 90 ℃, holding time of 72 h. Key words Gaomiaozi bentonite Al13-pillaring agent hydro-