Ni-Al间作用势对Ni75Al14Mo11合金原子有序化影响的微观相场模拟.pdfVIP

第25 卷第6 期 中国有色金属学报 2015 年6 月 Volume 25 Number 6 The Chinese Journal of Nonferrous Metals June 2015 文章编号：1004-0609(2015)06-1450-08 Ni-Al间作用势对Ni75Al14Mo11合金原子 有序化影响的微观相场模拟 马庆爽，靳玉春，赵宇宏，侯 华，王欣然，王 锟 ( 中北大学 材料科学与工程学院，太原 030051) 摘 要：采用三元微观相场动力学模型，研究第一到第四层Ni-Al原子间作用势对Ni 75Al 14Mo 11合金沉淀过程中原 子有序行为及γ′相沉淀的影响。结果表明：当第一层Ni-Al原子间作用势增大时，Al和Mo有序化和簇聚的程度和速 度增大；当第二层Ni-Al原子间作用势增大时，Al和Mo有序化和簇聚的程度和速度降低；当第三层Ni-Al原子间作 用势增大时，Al和Mo 的有序化和簇聚的程度和速度增大，相比之下沉淀后期较大的原子间作用势对Mo 的影响程 度较小；第四层Ni-Al原子间作用势对Ni和Al有序化和簇聚的影响与第二层原子间作用势的影响相同。第一、三层 Ni-Al原子间作用势增大，将促进γ′相的生成，且γ′相体积分数增大，而第二、四层原子间作用势对γ′相影响与第一、 三层的影响效果则相反。 关键词：微观相场；Ni 75Al 14Mo 11合金；γ′相；沉淀 中图分类号：TG 166.7 文献标志码：A Microscopic phase-field simulation for influence of Ni-Al interaction energy on ordering behavior of Ni75Al14Mo11 alloy atoms MA Qing-shuang, JIN Yu-chun, ZHAO Yu-hong, HOU Hua, WANG Xin-ran, WANG Kun (College of Materials Science and Engineering, North University of China, Taiyuan 030051, China) Abstract: The influence of Ni-Al interaction energy from the first layer to the fourth layer on the ordering behavior of Ni 75Al 14Mo 11 alloy atoms and the precipitation of γ′phase was investigated by the microscopic phase-field kinetic model. The results show that as the first Ni-Al interaction energy increases, the ordering and the clustering degree of Al and Mo atoms increase. As the second Ni-Al interaction energy increases, the ordering and the clustering degree of Al and Mo atoms decrease. As the third Ni-Al interaction energy increase, the degree and speed of the ordering and the clustering of Al and Mo atoms increase. Compared wit