气-液-液喷射反应萃取制备过氧化氢的过程.pdfVIP

第54 卷 第11 期 化 工 学 报 VoI. 54 N 11 2003 年11 月 JournaI of ChemicaI Industry and Engineering （China ） November 2003 研究简报 气-液-液喷射反应萃取制备过氧化氢的过程 1，2 1 1 1 1 1 吕树祥 王 莅 刘建国 颜廷哲 王亚权 米镇涛 1 2 （天津大学化工学院，天津300072 ； 天津科技大学材料科学与化工学院，天津300222 ） 关键词 蒽醌 过氧化氢 喷射萃取 喷射反应萃取 氧化率 萃取率 中图分类号 TO 123. 6 文献标识码 A 文章编号 0438 - 1157 （2003 ）11 - 1654 - 04 NOVEL REACTIVE EXTRACTION PROCESS FOR PREPARATION OF HYDROGEN PEROXIDE WITH BOTTOM AIR INJECTION L Shuxiang1，2 ，WANG Li1 ，LIU Jianguo1 ，YAN Tingzhe1 ，WANG Yaguan1 and MI Zhentao1 1 （School of Chemical Engineering and Technology ，Tianj in Uniuersity ，Tianj in 300072 ，China ； 2 School of Material Science and Chemical Engineering ，Tianj in Uniuersity of Science and Technology ，Tianj in 300222，China ） Abstract The extraction process for preparing hydrogen peroxide with bottom air injection in a spray coIumn was investigated. With the increase of air superficiaI veIocity ，extraction efficiency was improved remarkabIy and the height of transfer unit （HTU ）was IargeIy reduced. Extraction efficiency was 2—3 times higher than that of Iiguid- Iiguid extraction without air introduction ，and the HTU was onIy 1/ 2—1/ 3 of Iiguid-Iiguid extraction. Moreover ， the air-Iiguid-Iiguid reactive extraction system for preparing hydrogen peroxide uia anthraguinone was investigated. Oxidation reaction of the hydrogena