水热法制备Sb和Ta共掺杂的铌酸钾钠压电陶瓷粉体.pdfVIP

第 36 卷 第 2 期 Vol.36 No.2 Journal of Ceramics · 143 · 2015 年 4 月 Apr. 2015 第 36 卷 第 2 期 DOI：10.13957/ki.tcxb.2015.02.006 水热法制备Sb和Ta共掺杂的铌酸钾钠压电陶瓷粉体 代斐斐，张 帆，肖 倩 （沈阳化工大学材料科学与工程学院，辽宁 沈阳 110142） 摘 要：以Nb O 、NaOH和KOH为原料和矿化剂，Sb O 和Ta O 分别作为Sb和Ta的来源，采用水热法合成了Sb和Ta共掺杂的 2 5 2 3 2 5 铌酸钾钠，(K,Na)NbO3(KNN)无铅压电陶瓷粉体。借助XRD和SEM研究了掺杂对产物形貌和晶体结构的影响。结果表明， 当Sb掺杂量在2-8 mol%时，Sb扩散进KNN晶格中生成新的固溶体，产物为钙钛矿结构。Sb掺杂量固定在2 mol%， Ta掺杂量 在2-4 mol%时，KNN由正交相转变为四方相。随着Ta掺杂量的增加，粉体由3-4 μm的球形逐渐变为1-2 μm的立方体状。 关键词：水热法；铌酸钾钠；Sb和Ta共掺杂；无铅压电陶瓷 中图分类号：TQ174.75 文献标志码：A 文章编号：1000-2278(2015)02-0143-04 Hydrothermal Synthesis of Sb and Ta doped Potassium Sodium Niobate Piezoelectric Ceramic Powders DAI Feifei, ZHANG Fan, XIAO Qian (School of Materials Science and Engineering, Shenyang University of Chemical Technology, Shenyang 110142, Liaoning, China) Abstract:Sb and Ta doped (K, Na)NbO (KNN) lead-free piezoelectric ceramic powders were synthesized via hydrothermal method using 3 Nb O , KOH and NaOH as the main raw materials, Sb O as Sb source and Ta O as Ta source. The effects of doping of Sb and Ta on the 2 5 2 3 2 5 morphology and crystal structure of KNN were studied by XRD and SEM. The results show that when the Sb content changed from 2 mol % to 8 mol %, Sb could spread into the KNN lattice and form a new solid solution and the products were all of perovskite structure (K, Na) NbO3 . When the doping amount of Sb was fixed