《LiBH4Mg17Al12氢化物复合体系的放氢行为改善及其机制（英文版）》.pdfVIP

Trans. Nonferrous Met. Soc. China 24(2014) 152−157 Enhanced dehydrogenation performances and mechanism of LiBH /Mg Al −hydride composite 4 17 12 Le-yuan HAN, Xue-zhang XIAO, Xiu-lin FAN, Yun LI, Shou-quan LI, Hong-wei GE, Qi-dong WANG, Li-xin CHEN Key Laboratory of Advanced Materials and Applications for Batteries of Zhejiang Province, Department of Materials Science and Engineering, Zhejiang University, Hangzhou 310027, China Received 6 November 2012; accepted 1 April 2013 Abstract: Mg Al −hydride (abbreviated as MAH) was selected as a destabilization agent to improve de/rehydrogenation properties 17 12 of LiBH . 58LiBH +Mg Al −hydride composite was prepared by ball-milling. It is found that the dehydrogenation of ball-milled 4 4 17 12 LiBH /MAH composite presents a two-step reaction for hydrogen release. The composite starts desorbing hydrogen at about 300 °C 4 and yields 9.8% of hydrogen (mass fraction) below 500 °C. By adding MAH, the dehydrogenation kinetics of LiBH is improved and 4 the dehydrogenation temperature of LiBH4 is also lowered by 20 °C. High rehydriding capacity of 8.3% was obtained for the dehydrogenated composite in the first cycle at 450 °C. The XRD analysis shows the formation of MgB2 and AlB2 in the dehydrogenation process, which reduces the thermodynamics stability of LiBH system and is beneficial to the reversible hydrogen