9. SAKAI CHEMICAL INDUSTRY CO.- Hideo Tsujimoto.pdfVIP

Technical Information Sakai’s flame retardants Sakai chemical industry CO.,LTD general manager, technology department HIDEO TSUJIMOTO June 16-17, 2011 Denver, Colorado, USA 1 Contents Technical Information 1. Mechanism of combustion 2. Mechanism of flame retardants a. Mg OH 2 b. Melamine Cyanurate c. Intumescent flame retardants 3. Sakai’snew flame retardants a. MGZ-series b. MC-series c. SCFR-series 2 １． Mechanism of Combustion Technical Information ① Plastics 3 elements of combustion S ① Combustible substance o Thermal degradation l i d Combustible ② Thermal energy p H h a gases e ③ Oxygen s a e t D T i Radical generate r f a f u n s s i . o Fireproofing n R a d i a t i Combustion o n G Remove a s one element of combustion p h a s e ③Oxygen ②Thermal energy 3 ２．Mechanism of flame retardants Endothermic types Technical Information Mg OH 2 Melamine Cyanurete H O , N2 2 Decomposition gas E MGZ MC n d R o a t d Char promote ○ ー h i e a r t i Oxygen isolate ー ○ m o i n c Endothermic ○ ○ Thermal energy 4 ２．Mechanism of flame retardants Intumescent type Technical Information SCFR-series Phosphorus comp. ?Radical trap ?Char promote P:char promote radical trap N:inert gases Intumescent Intumescent Oxygen isolate Insulator effect layer i n T R Phosphorous Nitrogen s h a u e compd. compd. l r d a i t m a Char promote ○ ー i t o a i n l o Radical trap ○ ー n Oxygen isolate ー ○ Endothermic ○ ○ Thermal energy 5 Sakai’s Product Technical Information Flame retardant a. MGZ-1 MGZ-3 MGZ-6R Magnesium hydroxide Physical property Technical Information unit MGZ-1 MGZ-3 MGZ-6R Feature － High dispersion Fine particle Acid durability Particle size mm 0.8 0.1 1.5 Index of refraction － 1.57 ～ 1.58 1.57 ～ 1.58 1.57 ～ 1.58 Bulk density g/ml 0.30 0.18 0.40 Dehydrate temp. ℃ 372 369 380 TG-DTA － use 105 80 100 60 95 40 Electric wire, Film, D 90 20 % T Profile ,EMC etc. A t h 85 0 m g i e V W 80 -20 75 -40 JP B座机电话号码 70 -60 65 -80 0 100 200 300 40