CO2气体吸附剂.pdfVIP

Article /JPCC Amine-Functionalized Titania-based Porous Structures for Carbon Dioxide Postcombustion Capture Cindy C. Aquino,† Gilles Richner,‡ Maryline Chee Kimling,§ Dehong Chen,§ Graeme Puxty,‡ Paul H. M. Feron,‡ and Rachel A. Caruso*,†,§ †CSIRO Materials Science and Engineering, Private Bag 33, Clayton South, VIC 3169, Australia ‡CSIRO Energy Technology, P.O. Box 330, Newcastle, NSW 2300, Australia §PFPC, School of Chemistry, The University of Melbourne, Melbourne, VIC 3010, Australia ABSTRACT: An amine-grafted solid sorbent is a promising alternative to aqueous amine scrubbing for removing CO2 from the flue gas of coal power plants. In this study, phosphonic and carboxylic acids have been investigated as alternative anchor groups to trimethoxysilanes to synthesize amine-functionalized TiO2-based sorbents. Several supports, namely, mesoporous TiO2 beads, TiO2 nanoparticles (Degussa P25), and TiO /ZrO composite beads, and 2 2 a range of amines (1, 2, and 3 carbon-chain primary amine) have been assessed for CO adsorption at 30 °C and up to 101 kPa CO . 2 2 As a general trend, CO2 adsorption capacity increased with the carbon-chain length of the amine. Finally, materials functionalized with amino acids, L-glutamine or L-arginine, were investigated; the latter showed the highest CO2 adsorption capacity (0.4 mmol/ g at 30 °C and 20 kPa CO2) due to the higher pKa (12.10) of one of the ami