磷酸鋰鐵陰極材料.pptVIP

鋰電池 discharge SEI : solid electrolyte interphase Schematic open-circuit energy diagram of an aqueous electrolyte. ΦA and ΦC are the anode and cathode work functions. Eg is the window of the electrolyte for thermodynamic stability. A μALUMO (lowest unoccupied molecular orbital) and/or a μCHOMO (highest occupied molecular orbital ) requires a kinetic stability by the formation of an SEI layer. thermodynamic stability requires locating the electrode electrochemical potentials μA and μC within the window of the electrolyte, which constrains the open circuit voltage Voc of a battery cell to eVoc