《加料方式及底物浓度对Ti_MWW催化剂上环己酮氨肟化反应的影响》.pdf

27 7 2006 7 Vol. 27 No. 7 Chinese Journal of Catalysis July 2006 : 0253-9837(2006)07-0562-05 : 562~ 566 Ti-MWW 宋 芬, 刘月明, 汪玲玲, 张海娇, 吴海虹, 吴 鹏, 何鸣元 ( 华东师范大学化学系上海市绿色化学与化工过 绿色化重点实验室, 上海 200062) : T-i MWW . , T-i MWW , . , 99% , , . : ; T-i MWW ; T S- 1 ; ; ; : O643 : A Effects of Feeding Mode and Substrate Concentration on the Cyclohexanone Ammoximation over T-i MWW Catalysts SONG Fen, L IU Yueming, WANG Lingling, ZHANG Haij iao, * WU Haihong, WU Peng , HE Mingyuan ( Shanghai Key Laboratory of Green Chemistry and Chemical Processes, Dep artment of Chemistry, East China Normal University , Shanghai 0006 , China) Abstract: The liqui -phase ammoximation of cyclohexanone w ith ammonia an hy rogen peroxi e w as con uct- e over the Ti-MWW catalyst. The operating con itions of the reaction, especially the fee ing mo e of H2O2 greatly affecte the catalytic performance of T-i MWW. In a ition, the concentration of H O also affecte the 2 2 ammoximation reaction. U n er the optimum reaction con itions, the cyclohexanone conversion an oxime selec- tivity were both over 99%. Key words: titanosilicate zeolite; Ti-MWW zeolite; TS- 1 zeolite; cyclohexanone; cyclohexanone oxime; liqui - phase ammoximation , EniChem TS- 1 6 66 , ( CPL) . . ( HTS , ) ( TS- 1 ) . 2003 , 7 6 , 90% . . ( 999% ) ( 982% ) ( 28 t/ t) , , , [ 1] . , TS- 1 ( : 2005-12-28. : , , 1975 , . : . T el: ( 021) E-mail: pw u@ chem. ecnu. e u. cn. : , ( 20