《螯合剂与表面活性剂复合去除城市污泥中Cd_Cr_陈玉成》.pdf

中国环境科学 2003,24(1)：100~104 China Environmental Science 螯合剂与表面活性剂复合去除城市污泥中Cd 、Cr * 陈玉成1,2 3 1 ,郭 颖 ,魏沙平 (1.西南农业大学资源环境学院,重庆 400716；2.武汉大学资源与环境科学学院,湖 北 武汉 430072 ；3.重庆钢铁设计院,重庆 400013) 摘要：采用淋洗和振荡离心试验研究了螯合剂与表面活性剂等化学物质对城市污泥中Cd、Cr 去除的影响.柠檬酸(CTA)、EDTA 单一处理 污泥,对 Cd、Cr 的去除效果要优于十二烷基磺酸钠(SDS),且振荡更有利于污泥中 Cd 的去除,但淋滤与振荡对 Cr 的去除没有明显的差 异.CTA 对污泥中Cd、Cr 的去除率随介质浓度的变化特征符合一级方程,而EDTA 符合二级方程.SDS 可明显地改变螯合剂对Cd、Cr 的去 除效果.CTA 与SDS、EDTA 与SDS 复合,无论是顺序处理还是共同处理,对去除污泥中Cr 都表现为拮抗效应或独立效应,而对Cd 的去除 : 则表现出复杂的复合效应.综合考虑Cd、Cr 去除与氮素损失后,最优试验条件为0.3mol/L CTA 与0.01mol/L SDS,按1 10 固液比,依次振荡 2h,可去除59.2%的Cd 和50.91%的Cr,仅损失 13.47%的氮.污泥处理前有效态Cd、Cr 含量较高,经淋滤和振荡处理后,其活性有所降低,潜 在重金属供应能力以及对植物的危害潜力减弱. 关键词：螯合剂；表面活性剂；污泥；镉；铬；去除 中图分类号：X703 文献标识码：A 文章编号：1000-6923(2004)01-0100-05 Removal of Cd and Cr from municipal sludge by complexing of chelators and surfactants. CHEN Yu-cheng1,2, GUO 3 1 Ying , WEI Sha-ping (1.School of Environment and Resources, Southwest Agricultural University, Chongqing 400716, China；2.School of Environment and Resources Science, Wuhan University, Wuhan 430072, China；3.Chongqing Iron Steel Design Institute, Chongqing 400013, China). China Environmental Science, 2004,24(1)：100~104 Abstract：The leaching and vibration-centrifuge experiment were adopted to study the influence of chemicals such as chelators and surfactants on the removal of cadmium (Cd) and chromium (Cr) from municipal sludge. The removal effect of Cd and Cr by single treating of citric acid (CTA) or EDTA was higher than that by sodium dodecyl sulfonate (SDS), and vibration was more favorable for removal of Cd from the sludge; but the removal of Cr by leaching and vibration was not different markedly. The change