《两种不锈钢硫化氢环境下的应力腐蚀开裂行为研究》.pdf

耐蚀金属材料第十～届学术年会论文集 黑色金属 B一2l 两种不锈钢硫化氢环境下的应力腐蚀开裂行为研究★ 刘智勇。李晓刚．t超芳。郅青 (北京科技大学腐蚀与防护中心北京市腐蚀、磨蚀与表面技术开放实验室。北京100083) 摘 要： SCC的萌生孕育期较长，在pH较低的饱和H2s溶液中具有明显的SCC敏感性，其SCC敏感性随溶的pH 铁索体相间HIC裂纹，促进SCC萌生，其SCC为TGSCC。 关键词： 3Crl7Ni7M02N不锈钢；2205不锈钢；硫化氢；应力腐蚀开裂 中图法分类号TGl42 文献标识码A 文章编号 STRESSCORROSIoNCRACKⅣGBEHAⅥOURSOFTWO ML气TEALSINSULR匝)E HYDROGENSOI凡厂rIONS UU Z兔／yong,nXiaogang,DongChaofang。ZhiQing CorrosionandProtection ofScienceand labofCorrosionerosionand Center,UniversityTechnologyBeijing,Key surface 100083 techniqueBeijing，neijing Correspondent：UU Zh蜘ng．Tel：(010E-mail：163．com NationalNaturalScienceFoundation Supportedbysupported勿the ofChina． receivedOn ．inrevisedforra Manuscript and ABSTRACTStresscorrosion 3Crl7Ni7M02N cracking(scc)of steelsinacidic sulfidesolutionsWCiC slowSff_inrate U-bent hydrogen investigatedby test(SSRT)andspacim加 test．Resultsshowthatthetime￡oSCCfailurefor22晒stainless much thanthat steel(SS)was immersing longer for3Crl7Ni7M02NSS．2205SSwas toSCC砒alowerlevelinsaturated solution, highlysuscepfive pH H2S whiletheSCC decreased asthe increasedOtconcenWafionof decreasedin susceptibilityveryquicklypH H2S solutions．Tune幻failureforthe SSWaSwithin720hours．3Crl7NiTM02NSSshowed 3Crl7Ni7M02N high to$CCinsolutionswitha concentration and susceptibilitie H2S OVa1000ppmpH=4．5。however,the variedinasmallrate to and conce