水热条件对合成WO3纳米棒形貌与光吸收特性的影响傅小明.pdfVIP

40 1 人 工 晶 体 学 报 Vo.l 40 No. 1 2011 2 JOURNAL OF SYNTHETIC CRYSTALS February, 2011 WO 3 傅小明,杨在志, 徐 艳 (, 22 800) : , , W O XRDSEMTEM SAED, : W O , pH , W O pH 1. 5 240 72 h 100 nm W O , W O W O - , pH , W O : ; ; : O614. 61+ : A : 1000-985X( 2011) 01-0242-05 Influence ofHydrothermalCondition on theOpticalAbsorption Properties andMorphologies ofWO Nanorods 3 FUX iao-ming, YANG Zai-zhi, X U Yan ( The rd Departm ent of Suqian College, Suqian 22 800, China) (Received 12N ovember 2010, accep ted 8D ecember 2010) Abstract:WO nanorodsw ere synthesized by hydrothernalmethod using sod ium tungstate as raw material and potassium su lphate as assistant in strong acid system. The products w ere characterized by XRD, SEM, TEM and SAED and the effect of hydrothermal condition on the optical absorption properties and morphologies of productsw ere studied. The result ind icate that as the pH value, the reaction temperature and the reaction tmi e increasing, WO nanorods cou ld obtain easily by the hydrothernal cond ition. W O nanorods of less than 100 nm in the diameterw ere synthesized at 240 for 72 hw ith pH = 1. 5 by the hydrothernal condition. The crystalWO nanorods is homogeneous in the diameter. The optical absorption preoperties of the samples w ere characterized by UV-V IS. As the pH value, the reaction tmi e and the reaction temperature increasing, the optical absorption of synthesizedWO enhance gradually. ey words