CO_2直接合成碳酸二甲酯催化剂的研究进展.pdfVIP

32 2 Vol32 No. 2 2011 4 Journal of Chemical Industry Engineering Apr., 2011 CO2 宁英男, 唐 浩, 毛国梁 ( , 163318) : ( DMC) , , , , , , : : T Q22552 : A : 1006 906( 2011) Research progress of catalyst for direct synthesis of dimethyl carbonate from carbon dioxide NIN G Yingnan, TA NGH ao, MA OGuoliang ( College of Chemistry Chemical Engineering, Northeast Petroleum University , Daqing 163318, China) Abstract: Dimethyl carbonate ( DMC) is an import ant green chemical material, and it has been applied w idely in industry, agriculture and pharmaceut ical industry . DMC has a variety of synthetic methods, of which the phosgene methanol met hod, transesterification method and oxidat ion carbonylation have been industrialized, but t heir ow n shortcomings limit their scale. In recent years, t he method of synthesizing DM C using carbon dioxide and met hanol is researched and regarded as the greenest synt hetic method. The applicat ion of catalysts for this method and the research progress of the catalytic mechanism are presen ted, and recommendations on the problems of catalyst s are put forw ard. Key words: Carbon dioxide; Methanol; Dimethyl carbonate; Catalyst , , DM C , ( DM C) , , , [ 1] , , , , , , , , ; DM C , , : ( DM S) ; : ( 1954- ) , , , , ( MTBE) , , , , : , : zhaoyubo- 984928@ 126. com 36