修复石油类污染地下水的PRB反应介质研究张莹.pdfVIP

40 2 Vol. 40 No . 2 2010 3 Jour al of Jili U iversity Earth Scie ce Editio Mar. 2010 修复石油类污染地下水的PRB 反应介质研究 1, 2 1, 2 1, 2 1, 2 1 张 莹 , 张玉玲 , 张晟瑀 , 万玉玉 , 李浩旭 1. , 130026 2. , 130026 : 以石油类污染地下水为研究对象, 选用颗粒活性炭草炭土粒径为1 mm 和 3 mm 的页岩陶粒 泥岩陶粒高 土聚乙烯醇细砂和白砂等9 种材料进行PRB 反应介质筛选及其性能研究筛选实验结 果表明, 草炭土去除地下水中总石油烃的效果最好; 动态吸附实验结果表明, 在吸附1 h 时, 草炭土去除总 石油烃已经达到动态平衡; 通过热处理改性, 草炭土去除石油烃效果得到提高, 在 130 热处理2 h 去除 石油烃效果最好; 颗分后吸附实验结果表明, 在粒径 2 mm 范围内, 草炭土吸附效果均十分显著在此基 础上进行吸附石油烃前后草炭土的微观结构观察及理化性质分析以上研究表明, 草炭土作为 PRB 反应 介质处理石油类污染地下水具有良好的应用前景 : 石油类污染; 地下水; PRB 反应介质; 总石油烃; 吸附; 草炭土 : X523 : A : 1671-5888 2010 02-0399-06 Study on PRB Reactive Media in Remediation of Petroleum Contaminated Groundwater ZHA NG Yi g1, 2 , ZHANG Yu-li g1, 2 , ZHANG She g-yu1, 2 , WAN Yu-yu1, 2 , LI H ao-xu1 1. Col le ge of E nv ir onmen t and Re sour ces , J i li n Univ er s ity , Ch angch un 130026, Chi na 2. I nst it ut e of Wat er Reso urc es and Env i ronment , J i l in Univ ers i ty , Chang chun 130026, Ch ina Abstract: Ni e ki ds of materials, i cludi g gra ular activated carbo GAC , peat, shale- haydite, mudrock ceramicite with size of 1 mm a d 3 mm, kaoli clay, polyvi yl alcohol, fi e sa d a d w hite sa d w ere comparied for PRB reactive media testi g. T he results of the experime t show ed that the reductio of TPH i grou dw ater by peat media w as optimal. T he results of dy amic adsorptio experime t show ed that it reached adsorptio equilibrium after 1 h. The removal effect of TPH w as improved by heat-treatme t of peat. T he removal effect w as optimal u der the co ditio of 130 a d 2 h. The particle classificatio test results show ed that the removal effect w as sig ifica t w he the particle size w as less tha 2 mm . O the basis of above, microstructure of peat w as observed a d physicochemical property of peat w as a alized. It had a good applicatio prospects for PRB w ith the peat as the reactive media i the remedy area of petroleum co tami ated grou dw ater . Key