《A Pioneering Experimental Study on the Batch Crystallization of the Citric Acid Monohydrate》.pdfVIP

《A Pioneering Experimental Study on the Batch Crystallization of the Citric Acid Monohydrate》.pdf

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《A Pioneering Experimental Study on the Batch Crystallization of the Citric Acid Monohydrate》.pdf

J.Chem.Chem.Eng.8(2014)611-620 A C PioneeringExperimentalStudyontheBatch rystallizationoftheCitricAcidMonohydrate EnzOBOnacci DepartmentofMathematicsandPhysics,ScientificHighSchool“G.B.Grassi”ofLatina,Latina04100,Italy Received:May12,2014/Accepted:June04,2014 /Published:June25,2014 Abstract:Citricacidisan importantorganicsubstancewhosemarketingconcernsvariousfields.Nevertheless.until1997the scientificliteraturerepoaedlittleinformationabouttheprocessofcrystallizationbycoolingthroughwhichthecommercialproduct isobtained.Inparticular,theavailablestudieswereaimedtoinvestigateonlythekineticsofnucleationna dcrystalgrowthneglecting someeffectiveaspectsoftheindustrialcrystallization inmechanically stirreda1)paratus.Inorderto filIthatsci.tech gap,the DepartmentofChemicalEngineeringattheUniversity L‘‘aSapienza’ofRomedecidedtoleadalongandmeticulousexperimental researchonthecrystallizationindiscontinuous(batch)ofCAM (citricacidmonohydrate)iBtheallotropicfoFI/1thatisstableatroom temperature.Duetothenumberofpeopleinvolvedinthatpioneeringwork.crariedoutinthehistoriclaboratoriesof “LaSapienza’ (FacultyofEngineering),andmotivatedbythepublicationofrelatedM.Sc.dissertationsandreserachpapers,suchcollectiveeffort wascalled “SchoolofIndustrialCrystallization”.Among the graduate studentsin Chemica1Engineering that l7 years ago participatedinthatfruitfulexperiencetherewasalsotheauthorwho.underthesupervisionofProf.BarbaraMazzarotta.hadthe specifictaskofassessing theeffectson CAM ofchanging thecrystallizationoperating conditionsuntiltheiroptimization;the achievementsarebrieflyillustratedinthispaper. Keywords:Batchcrystallization,CAM ,informativeessay,crystalsizedistribution,Zwieteringcorrelation. 1.Introduction Society[10]andinthe2011IYC (InternationalYear ofChemistry)asinvitedlecture[11];thenitreceived ThispaperreportsthemainresultsofaM

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