Promotional effect of N-doped CeO2 supported CoOx catalysts with enhanced catalytic activity on NO oxidation》.pdf

Journal of Molecular Catalysis A: Chemical 398 (2015) 344–352 Contents lists available at ScienceDirect Journal of Molecular Catalysis A: Chemical j o u rn al h omepage: w w w. elsev /locate/molc ata Promotional effect of N-doped CeO2 supported CoOx catalysts with enhanced catalytic activity on NO oxidation Yang Yu a,b , Qin Zhong a,b,∗ , Wei Cai a,b , Jie Ding a,b a School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, PR China b Nanjing AIREP Environmental Protection Technology Co., Ltd Nanjing, Jiangsu 210091, PR China a r t i c l e i n f o a b s t r a c t Article history: A series of neoteric CoOx /N-doped CeO2 catalysts were synthesized by partly substituting the lattice Received 23 August 2014 oxygen of CeO with nitrogen by a simple g-C N -modified sol–gel method and comprehensively char- 2 3 4 Received in revised form acterized by XRD, H2 -TPR, XPS, BET, TEM, TG, UV–vis DRS, PL, EIS, NO(O2 )-TPD and EPR. The results 24 December 2014 demonstrated that: (1) The N-doped catalysts showed larger surface areas and pore volumes, which Accepted 1 January 2015 were favorable for the adsorption of reactant gas; (2) Replacing O with N could promote the reduction Available online 3 January 2015 of resultant catalysts and assist cobalt oxide i