Remarkable activity of AgAl2O3cordierite catalysts in SCR of NO with ethanol and butanol》.pdf

Applied Catalysis B: Environmental 140–141 (2013) 691–699 Contents lists available at SciVerse ScienceDirect Applied Catalysis B: Environmental j o u r n a l h o me p a g e: w w w. elsev /locate/apc atb Remarkable activity of Ag/Al O /cordierite catalysts in SCR of NO with 2 3 ethanol and butanol Pavlo Kyriienko a,∗ , Nataliia Popovych a , Sergiy Soloviev a , Svitlana Orlyk a , Stanislaw Dzwigaj b,c a L.V. Pisarzhevsky Institute of Physical Chemistry of the NAS of Ukraine, 31 Prosp. Nauky, 03028 Kyiv, Ukraine b UPMC Univ Paris 06, Laboratoire de Réactivité de Surface, Case 178, Site d’Ivry-Le Raphaël, 3 rue Galilée, 94200 Ivry sur Seine, France c CNRS-UMR 7197, Laboratoire de Réactivité de Surface, Case 178, Site d’Ivry-Le Raphaël, 3 rue Galilée, 94200 Ivry sur Seine, France a r t i c l e i n f o a b s t r a c t Article history: Structured silver–alumina catalysts were prepared by the one-step deposition of Al2 O3 directly on the sur- Received 16 February 2013 face of cordierite block matrices with subsequent incipient wetness impregnation of Al O /cordierite with 2 3 Received in revised form 24 April 2013 an AgNO3 aqueous solution. The catalysts were characterized by BET, XRD, XPS and FTIR spectroscopy with Accepted 30 April 2013 CO and pyridine as molecule probe, d