基于钯金纳米颗粒催化性能检测双氧水-毕业论文设计.docVIP

湖南文理学院芙蓉学院 本科生毕业论文(设计) 题 目： 基于钯金纳米颗粒催化性能检测双氧水 学生姓名： 姚泽顺 所在学院： 芙蓉学院 学 号： 专业班级： 应化1001班 指导老师： 沈广宇 完成时间： 2014年5月 目 录 摘要 2 关键词 2 Abstract 3 Keywords 3 1引言 4 2实验部分 5 2.1实验试剂 5 2.2主要仪器 5 2.3材料的制备 5 2.3.1 PBS及Piranha 的制备 5 2.3.2钯金纳米颗粒的制备 6 2.4电极的处理 6 2.5电极的修饰 6 2.6检测方法 6 3结果与讨论 6 3.1钯金纳米颗粒的表征 7 3.2电极修饰过程的表征 7 3.3钯金纳米颗粒的催化性能 8 3.4双氧水的检测 9 4结论 10 参考文献 12 致 谢 14 基于钯金纳米颗粒催化性能检测双氧水 姚泽顺 芙蓉学院 应化1001班 摘要 通过近些年的研究发现，利用氧化还原法对双氧水的定量分析已经落后了，基于双氧水的还原性，用KMnO4双氧水的氧化性，采用碘量法但是这样经典的方法存在着种种影响因素，如操作周期长，分析费时、费力的缺点。本实验采用电化学的方法来测量双氧水的浓度，简单而又方便。在工作电极上固定钯金纳米颗粒和壳聚糖的混合物，在配好的PBS溶液中滴加浓度的双氧水，在某个浓度范围内，电信号的变化随双氧水浓度变化成线性关系本实验能更好、更快的测定双氧水的浓度，摒弃了繁琐步骤，值得推行。 关键词 钯金纳米颗粒；双氧水；检测；催化 Catalytic properties of palladium nanoparticles based on the detection of hydrogen peroxide Yao Zeshun Furong College, Applied Chemistry, Class 1001 Abstract The recent study found，oxidation using previous reduction method for the quantitative analysis of hydrogen peroxide has lagged behind. Gender based on hydrogen peroxide, method for determination of hydrogen peroxide content of: The reduction of hydrogen peroxide, Using KMnO4 titration 5H2O2+2MnO4+6H+→2Mn2++5O2+8H2O The oxidation, using iodimetry H2O2+2I-+2H+→O2+2H2O；I2+2S2O32-→2I-+S4O62-+H2O. But this classic has various influence factors, As the operating cycle is long, time-consuming, laborious defects analysis. The experimental concentration by electrochemical method to measure hydrogen peroxide, simple and convenient. The mixture on the working electrode is fixed on the palladium nnanoparticles and chitosan. In the PBS solution with good added known concentrations of hydrogen peroxide. As the working electrode with the fixed palladium nanoparticles of gold electrode, a Pt electrode as auxiliary electrode, a saturated calomel electrode (CSCE) as the reference electrode, to different concentration measurement solution of hydrogen peroxide。To summarize the signal by changing the electrical signals of electrochemical workstation of the law,