La0.75-xPrxMg0.25Ni2.9Co0.4Al0.2(x=0～0.4)电极合金的微观结构及电化学性能.pdfVIP

构及电化学性能 高金良·一， 张羊换2，任江远1，王新林2，赵栋梁2，葛启录2 (1．包头三德电池材料有限公司，内蒙古包头014010；2．北京钢铁研究总院功能材料研究所，北京100081) 交流阻抗谱，研究了Pr替代对铸态及快淬态合金微观结构及电化学性能的影响。结果表明，铸态及快淬态合金具有多 相略有增加。Pr的替代提高了铸态及快淬态合金的循环稳定性，但使合金的容量有所下降。铸态及快淬态合金均有优 良的活化性能。合金的循环寿命随淬速的增加而增加。 关键词：La-Mg—Ni系贮氢合金；快淬；微观结构；电化学性能 912 002—087 中图分类号：TM 文献标识码：A 文章编号：1 X(201 0)04—0382～05 Microstructuresandelectrochemicalofas—castand performance quenched alloys 2 GAO Xin·lin2，ZHAO Jin-lian91’2，ZHANGYang—huan2，RENJiang—yuanl，WANG Dong—lian92，GEQi—lu rJ．BaotouSantoku Co．，Ltd，Baotou BatteryMaterial Neimenggu014010，China； ofFunctionaIMaterialResearch，CentralIronandSteelResearch 2．Department Institute,Beijing100081，China) Abstract：Inorderto theelectrochemicalof improve cyclestability La—Mg—Nj storage Lainthe was substituted alloy，the alloy partially byPr．Lao．75--尸L．Mg嘀Ni29Coo4AIo2(x=0-0．4)hydrogen storage were and electrochemicalandmicrostructureofthe alloys preparedbycastingrapidquenching．The performance as-castand weredeterminedandmeasured．InthemeantimetheEISoftheas—castwere quenchedalloys measured．ThePr the effectsof substitutionon microstructureandelectrochemicaloftheas-castand