钛酸铋钠系无铅电陶瓷固溶改性研究.pdf

其压电常数在x=0.02 时达到最大值，d33=119 pC/N 。 关 键 词：钛酸铋钠；准同型相界；介电弛豫；固溶改性 研究类型：应用基础研究 万方数据 Subject : Study on Property Improvement of NBT-based Lead-free Piezoelectric Ceramics Specialty : Material Science Name : Wang Jin (Signature) Instructor: Du Huiling (Signature) Abstract Bismuth Sodium Titanate Na0.5Bi0.5TiO3 (abbreviated NBT) is a ferroelectric ceramic that has the A-site complex perovskite type structure. In this paper, NBT-based ceramics with optimized the morphotropic phase boundary compositions were prepared by the conventional solid state reaction. The dielectric relaxation feature, phase transition feature and material composition on the role of the law of ferroelectric and piezoelectric properties been investigated by analysised the structure of perovskite structure of components. The new lead-free piezoelectric materials with high piezoelectric and ferroelectric activity were prepared. The lead-free piezoelectric ceramics NKBT-LBT and NKBBT-LBT were prepared by solid solution with Li0.5Bi0.5TiO3 into Na0.4K0.1Bi0.5TiO3 and Na0.44K0.04Bi0.48Ba0.04TiO3 ceramics. In the study of their composition range, the X-ray diffraction (XRD) analysis revealed that the two sets of ceramic systems form a single perovskite structure, and the morphotropic phase boundary (MPB) between the rhombohedral and tetragonal phases of NKBT-LBT was identified in the composition range of 0.08≤x≤0. 10, and the morphotropic phase boundary