用于PVC粘接双组份聚氨酯胶粘剂合成的研究.pdf

Subject :Studyon Synthesis of Two-Component Polyurethane Adhesive for PVCbonding Specialty :Material Physics andChemistry Name :DuanXuelei (Signature) Instructor :LiHuilu (Signature) ABSTRACT Polyurethane adhesives contain strong polarity, lively chemical and isocyanate groups and ammonia ester groups which can react with lively hydrogen groups to form the fine chemical bond firmly. Polyurethane adhesives have a good low temperature resistance,good abrasion resistance, water resistance,solvent resistance,medicinal chemical resistance and has been used widely. Two-componentpolyurethane was employed asthe adhesive forpolyvinyl chloride (PVC). Due to the strong polarity, the low surface energy of PVC,the adhesive was required to be of adjusted performance , high adhesion strength and wide bond range.This article used 4,4-diphenylmethane diisocyanate (MDI), trimethylolpropane (TMP), polyether polyols as raw materials to synthesize the two part of two-component polyurethane: hydroxyl components (the main agent) and isocyanate components (curing agent). Through the test of the content of isocyanate groups ,viscosity and FI-IR, effects of synthesis of two components reaction were studied below:the mole ratio of MDI/polyether polyols was 2.5, the reaction temperature was 90 ℃ and reaction time was 3 h ,under that conditions good hue, proper viscosity agents can be prepared;good performance, stability, good curing agent can be synthesizedwhen pretreat raw material until its moisture content less than 0.05%;polyols was fed into MDI by many times; the mole ratio of the MDI/TMP was between 3.1~3.3; elevate temperature sectionally and heat insulating temperature was controlled at (80±5) ℃, and the whole reaction time was in two hours or so;add dibutyltion dilaurate ( DBTDL ) in the late