石墨烯与壳聚糖的纳米复合材料性能及其表征.docVIP

摘 要 本文采用液相法制备石墨烯/壳聚糖复合材料，将石墨烯按不同比例加入到百分比为2wt%的壳聚糖醋酸溶液中，用磁力搅拌6小时后再用超声处理20分钟，使氧化石墨烯分散均匀，脱泡，将混合液倒在器皿内放在鼓风机中室温下烘干，即可得到比例为石墨烯含量为0.5wt%，1wt%，2wt%,3wt%,4wt%氧化石墨烯/壳聚糖纳米复合材料膜。利用做好的复合材料膜样品进行TG、红外、DSC、XRD、力学性能测试。结果表明：石墨烯加入到壳聚糖中表现出复合材料的热稳定性明显提高。其符合材料的熔点相对于纯CS也有明显提高。随着石墨烯的逐渐加入，CS/GO复合材料Tg也会增加。与纯壳聚糖和氧化石墨烯相比，在壳聚糖/氧化石墨烯纳米复合材料的光谱中，在1550cm-1处的-NH2吸收振动和在1730cm-1处的属于羧基的C=O伸缩振动两个峰都消失。石墨烯通过超声波处理，彻底剥离，形成单片层的石墨烯，在壳聚糖基体中分散良好。随着石墨烯含量的增加，CS/GO复合材料的杨氏模量和拉伸强度有明显的改善。但另一方面，在一定程度上使复合材料的断裂伸长率和韧性降低。 关键词：石墨烯，壳聚糖，复合材料Abstract This paper was prepared by liquid graphene / chitosan composite graphene different proportion to the percentage of added 2wt% acetic acid solution of chitosan, with a magnetic stirring for 6 hours and then sonicated for 20 minutes, the oxidation graphene dispersed, degassing, the mixture was poured in containers placed inside the blower drying at room temperature, you can get a ratio of graphene content is 0.5wt%, 1wt%, 2wt%, 3wt%, 4wt% graphite oxide ene / chitosan nanocomposite membranes. Make use of composite membrane samples TG, IR, DSC, XRD, mechanical testing. The results showed that: in graphene added to chitosan composites exhibit significantly improved thermal stability. Compliance with respect to the melting point of pure CS is also significantly improved. Was gradually added with graphene, CS / GO composite Tg will increase. Pure chitosan and graphene oxide compared to the chitosan / graphene oxide nanocomposite spectrum in at 1550cm-1 and a-NH2 vibration absorption at 1730cm-1 C = O belonging to a carboxyl group stretching two peaks disappear. Graphene by ultrasonic treatment, completely stripped, single layer graphene is formed in the chitosan matrix well dispersed. With increasing content of graphene, CS / GO composite Youngs modulus and tensile strength are significantly improved. On the other hand, to a certain extent, so that the composite fracture elongation and toughness. Keywords：Graphene, chitosan, composites目 录 第1章 概 论 1 1.1 课题背景及意义 1 1.2 本课题及相关领域的国内外现状