《半胱氨酸-β-环糊精同时解吸去除复合污染土壤中氰草津和镉的研究 Simultaneous Desorption Removal of Cyanazine and Cadmium from Co-contaminated Soils with Cysteine-β-cyclodextrin》.pdfVIP

ofAnhui 责任编辑刘月娟责任校对卢瑶 安徽农业科学，Journal A面．Sci．2013，41 33 ：12854—12858 半胱氨酸一D一环糊精同时解吸去除复合污染土壤中氰草津和镉的研究 王光辉，胡苏杭，黄婷 东华理工大学水资源与环境工程学院，江西抚州344000 明，CCD在保留B—CD原有空腔结构的同时还增加氨基、羧基及巯基，CCD能同时实现对氰草津的包结作用和镉的配位作用。增溶试验 研究表明，CCD对氰草津和碳酸镉有明显的增溶效应，10g／LCCD对氰草津的增溶倍数可达2l倍；碳酸镉的表观溶解度随着CCD浓度 的增加而增加，当CCD浓度为JO∥L时，水溶液中镉离子的浓度为599mg／L。10g／LCCD对复合污染土壤中氰草津和镉解吸去除率 10 93和0．010 分别为8l％和89％，解吸过程符合准二级动力学规律，解吸动力学常数分别为0．004 g／ mg·min 。pH的降低和CCD 初始浓度的增加有利于复合污染土壤中氰草津和镉的解吸。 关键词半胱氨酸一B一环糊精；氰草津；镉；复合污染土壤；解吸 181．3 中图分类号s 文献标识码A 文章编号0517—6611 2013 33—12854—05 SimultaneousRemovalof andCadmiumfromCo-contaminatedSoils诵tlI Desorption Cyanazine Cysteine-睁cyclodextrin WANG etal ofWaterResourcesandEnvironmental ChinaInstituteof Guang·hul College Engineering，East gxi344000 AbstractOnthebasisof novel thereactionof with p·eyclodextrin，aeysteine—B—cyclodextrin CCD wassynthesizedby 3-cyclodextrincys— infrared teine．The thatthe inner was inCCDand and wereadded． 8pe孔瓜demonstrated cavity original kept amino，carboxylsulflaydrylgroups CCDcan andcadmium．Theresultsfromsolubilization showedthatCCDhasobvioussolubiliza— simultaneously60mplexcyanazine experiments tionfor and carbonate．Theof in10 ofCCDwasenhancedabout2 the cyanazinecadmium solubilitycyanazineg／L 1一fold，andapparentaque— OUSsolubilitiesofcadmiumcarbonatearealso increasedwith CCD theconcentrationofCCDreached obviously increasingconcentration，when 10g／L，the cadmiumconcentrationwas599 concentrationof10 hasaremoval of81％and89％for aqueous mg／L．At g／L，CCD efficiency and thecombinedcontaminatedsoil．The ofCCDfor andcadmiumfrom desorption cyanazinecadmium，respectively，from process cyanazine CO—contaminatedsoilfollowedthe kinetic kinetic constantsof andcadmiuminsoilswere pseudo—second·ordermodel，thedesorption cyanazine 0．00493and0．010l and CCDconcentrationwerebeneficialtothe of and pH high desorptioneyanazine g／ mg．min ，respectively．Low fromco．contaminatedsoil． cadmium words Cysteine—B—cyclodextrin；Cyanazine；Cadmium；Co—contaminated Key soil；Desorption 土壤是人类赖