《Synthesis and Characterization of a Novel One-dimensional Metal Organic Compound》.pdfVIP

24 卷7 期 结 构 化 学 JIEGOU HUAXUE Vol. 24, No. 7 2005. 7 Chinese J. Struct. Chem. 809~815 Synthesis and Characterization of a Novel One-dimensional Metal Organic Compound HU Juan GAO Qiu-Ming (State Key Laboratory of High Performance Ceramics and Superfine Microstructures, Shanghai Institute of Ceramics, The Chinese Academy of Sciences, Shanghai 200050, China) ABSTRACT A novel metal organic compound of Zn2+ coordinated with 4,5-diazafluorene- 9-one-N (C H N ) has been synthesized under solvothermal condition. Single-crystal X-ray 2 22 12 6 diffraction analysis showed that the compound is a one-dimensional zig-zag chain structure combined by Cl H–C bonds. The crystal is of orthorhombic, space group Pnna, C H N Cl Zn, 22 12 6 2 M = 496.65,a = 8.1132(13),b = 18.983(3),c = 13.116(2) ,Z = 4, V= 2020.2(5) r 3 3 = 1.504 mm 1, F(000) = 1000, T = 293(2) K, the final R = 0.0626 and ,D = 1.633 g/cm, c wR = 0.1474 for 2390 unique reflections and 150 parameters with I 2s(I). The refinement method was full-matrix least-squares on F2 with GOF = 0.951. This compound was also characterized by FT-IR, Raman, UV-vis spectra, and TG-DTA. Keywords: zinc, 4,5-diazafluorene-9-one-N , one-dim