《Synthesis and Crystal Structure of Cu(II) Complex with 2,9-Bis(n-2#39;,5#39;- diazaheptanyl)-1,10-phenanthroline》.pdfVIP

23 卷7 期 结 构 化 学 JIEGOU HUAX UE Vol. 23, No. 7 2004. 7 Chinese J. Struct. Chem. 778~782 Synthesis and Crystal Structure of Cu(II) Complex with 2,9-Bis(n-2´,5´- diazaheptanyl)-1,10-phenanthroline LI Feng-Hua LIU Tian-Fu LIN Hua-Kuan ZHU Shou-Rong WANG Zhong-Ming (Department of Chemistry, Nankai University, Tianjin 300071,China) ABSTRACT The Cu(II) complex with the ligand 2,9-bis(n-2´,5´-diazaheptanyl)-1,10-phenan- throline (L) has been synthesized and characterized by single-crystal X-ray diffraction. It crys- tallizes in the monoclinic system, space group P2 /n with a = 12.549(4), b = 13.544(4), c = 1 3 16.767(5) Å, â = 107.179(5), C H Cl N CuO , M = 642.98, V = 2722.5(13) Å , Z = 4, D = 22 32 2 6 8 r c 3 1 1.569 g/cm , ì = 1.056 mm , F(000) =1332, the final R = 0.0733 and wR = 0.1581. The X-ray analysis revealed that the Cu(II) ion is coordinated by six nitrogen atoms of the ligand, in which two nitrogen from phenanthroline and another two from the imine groups near phenanthroline are in the equatorial plane while the two from imine groups at the end of both a