铒离子掺杂固体荧光材料光谱性质研究.pdf

讨论了2H,in,453,,2这样处于热平衡中的两个能级的量子效率的计算方 法，进而计算了它们的量子效率，并与其它材料进行了比较。 我们的研究结果表明，这两种材料45321和2x,121量子效率远小于 I，难以利用激发4S3n然后热激发到2Htln，通过2H,;二辐射跃迁携带 走晶格振动能的方法实现制冷。探索这种机制的反Stokes荧光制冷应 该在具有小的声子能量(多声子弛豫可以忽略)、低掺杂浓度(不出现浓 度碎灭)的材料中进行。 关键词:J-O参数;ZBLAN玻璃;MFT玻璃;反斯托克斯荧光;量 子效率 Abstract ThisworkwassupportedbytheNationalScienceFoundationof China(GrantNo,andtheStateKeyProjectofBasicResearch ofChina(GrantNo.61998061309) SinceEpsteindemonstratedthefluorescentcoolingeffectof0.5Kin ytterbium-dopedfluorozirconateglassesin1995,theresearchesof anti-stokesfluorescentcoolinginsolidmaterialshavereceivedgreat attention.Thecoolingeffectisobtainedbyexcitingthesampleata wavelengthslightlylongerthantheaveragefluorescencewavelength.The balancebetweentheemittedandabsorbedpowersrequiresthatthe thermalenergybetakenfromtheglass.Comparedwithconventional coolingmethods,thefluorescentcoolinghavetheadvantagesofhigh stability,nonoiseandnopollution.However,oncurrentstatusthecooling efficiencyisverylow,onlyabouttwopercent.Thereasonforthelow coolingefficiencyisthatsingleexcitedstatesdifferentStarksplitting energylevelhasverysmallenergygapwhichleadtonotmuchdifference intransitionprobability.Atthesametime,thealternativeforcooling materialislimitedS‘opeoplebegintostudyiftheycanusetwoexcited statesofrareearthmaterialstoobtainfluorescentcoolingeffects Theup-convertedgreenemissionofEr3correspondingto2Ht1rz.4S3rz ~411512emissionofthetrivalenterbiumionhasbeenextensively investigated.TheenergygapbetweenZH，。H22111and4S3rzisaboutsome hundredswavenumbers,whichisintherangeofphononenergy.Itiswell knownthatthe4S3nand2H11fzlevelsarealwaysinthermalequilibrium andtherelativeintensityo#the4532andZH1V2emissionsistemperature dependent.So,muchattentionhasbeenpaidtotheprobabilityofrare earthion扮+forfluorescentcooling. Inourwork,wehaveprocessedZBLAN:Er3andMFT:Er3`glasses Withthesesamples,wehaveinvestigatedthetemperaturedependen