BittevordemAusfüllenunbedingtMerkblattundbeigefügte.docVIP

BittevordemAusfüllenunbedingtMerkblattundbeigefügte.doc

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BittevordemAusfüllenunbedingtMerkblattundbeigefügte.doc

Application Form Basic Information Xia An Hongwei Xiang Name Advisor Name Datong City, Shanxi Province 27, 01, 1979 Place of Birth Date of Birth Female PhD. Gender Degree anbicheng@126.com Telephone E-mail Effect of some preparation chemistry factors on iron-based catalysts structure and Fischer-Tropsch synthesis performances Title of thesis Abstract of the thesis The Fischer-Tropsch synthesis (FTS), which converts coal, natural gas biomass into clean liquid fuels and chemicals, is considered as an effective solution to the problem of finding suitable substitutes for liquid fossil fuels. Recently, with the industrial application of this technology in Sasol and Shell, more and more energy industry starts to use FTS to meet the petroleum shortage. It is well known that the research and development of catalysts play an important role in the process of Fischer-Tropsch synthesis. The use of iron-based catalysts is attractive due to their high FTS activity as well as their water-gas shift (WGS) reactivity, which helps make up the deficit of H2 in the syngas from modern energy-efficient coal gasifiers. The present work chooses FeCuK/SiO2 as the research object. The characterization technologies of inductively coupled plasma emission spectroscopy (ICP-AES), N2 physisorption, X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), thermal gravity (TG), temperature-programmed reduction (TPR), temperature-programmed desorption (TPD) and M?ssbauer effect spectroscopy (MES) are used together to study the effect of residual sodium, sodium addition, SO42- addition and the incorporation manner of Cu promoter on iron-based catalysts in the preparation of the catalysts. The purpose of this study is to provide the basic information for industrial application. The results and corresponding conclusions obtained in this work are summarized as follows: The residual sodium means remaining in the catalyst if

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