Naturalgasmakeslifebetter.pptVIP

in situ FTIR C4H4S···H-O-Al thiophene species symmetric C=C stretching vibration 1401 cm-1 is assigned to the hydrogen bond (C4H4S···H-O-Al) formed between S atom and the surface hydroxyl groups of ?-Al2O3 1408 cm-1 is attributed to a weakly bonded, high-coverage thiophene species whose adsorption manner on alumina surface is not known 1429 cm-1 is assigned to the symmetric C=C stretching vibration in thiophene absorbed on coordinately unsaturated Mo sites.It is related with the amount of uncoordinated Mo sites in situ FTIR the adsorption of thiophene on the surface of sulfided Mo/?-Al2O3 catalyst is stronger than on ?-Al2O3 support. But both adsorptions are weak chemisorptions, which can be desorbed under high vacuum the results of in situ FTIR study confirm that thiophene can be chemically adsorbed on catalysts through the coordination of S atom, C =C and C—C with the unsaturated Mod+ sites located on the edge planes of MoS2 like structures, i.e. forming complexes 1–4 in situ FTIR in situ FTIR Relationship between the hydrodesulfurization of thiophene, dibenzothiophene, and 4,6-dimethyl dibenzothiophene and the local structure of Co in Co–Mo–S sites: Infrared study of adsorbed CO P. Castillo-Villalón et al. / Journal of Catalysis 294 (2012) 54–62 in situ FTIR The infrared analysis of adsorbed CO has the advantage of clearly distinguishing the surface Co–Mo–S sites from other contributions in the spectrum CO adsorbs on the promoted sites in situ FTIR The catalyst was sulfided in situ at 673 K and cooled down to room temperature in the H2S(15%)/H2 stream The sulfided catalyst was then outgassed under vacuum at 723 K for 2 h (5 K/min ramp) and cooled down to100 K using liquid nitrogen Calibrated doses of CO at pressures of 0.2, 0.5, 1, 2, 2, 5, 10, 20, 20 Torr measured with a MKS-HPS digital Pirani vacuum sensor with 1% resolution and 5% of the indicated pressure of reproducibility (corresponding 0.07, 0.12, 0.20,0.37, 0.37, 0.8, 1.69, 3.35, 3.35 μmole of