清华大学博士论坛会议论文集16——环境、污水、能源.doc

连续流双污泥－诱导结晶工艺脱氮除磷试验研究 史静，吕锡武* （东南大学能源与环境学院，南京 210096） 摘要：针对传统污水处理脱氮除磷工艺碳源不足、聚磷菌与硝化菌泥龄矛盾、磷资源无法有效回收利用等问题，开发出“双污泥－诱导结晶”新型工艺，对其连续流脱氮除磷和去除有机物的性能进行了考察。结果表明：当进水COD为152～237mg?L-1，TP为3.92～7.mg?L-1，TN为31.3～50.5mg?L-1，C/N比约为3.91～5.1时，COD、TN和TP平均去除效率分别为93.2%、71.%和95.7%。厌氧段COD去除量约占系统COD去除总量的85.9%。结晶在除磷过程中起着重要作用，在侧流比为33.3%的情况下，结晶除磷量平均约占总除磷量的81.5%。TN的去除主要由缺氧池承担，厌氧池、硝化池、缺氧池、后置曝气池TN去除量约占系统TN去除总量的31.7%、11.4%、54.9%和2.0%。后置曝气池对超越污泥中COD和氨氮的去除有重要作用。 关键词：反硝化除磷；双污泥；结晶；脱氮除磷 Nitrogen and Phosphorus Removal in a Continuous-Flow Two-Sludge and Induced Crystallization Process Shi Jing , LU Xi-wu (School of Energy Environment, Southeast University, Nanjing 210096, China) Abstract: To solve the problems of traditional nitrogen and phosphorus removal processes, like lack of carbon source, SRT contradictions and low efficiency of phosphorus reuse and recovery, a two-sludge and induced crystallization process was invented. Based on a lab-scale experiment, the characteristics of phosphorus, nitrogen and organic matter removal in the process were studied. The results indicated that under the condition of influence COD, TN, TP and C/N were 152～237mg?L-1, 3.92～7.mg?L-1, 31.3～50.5mg?L-1 and 3.91～5.1, the average removal efficiencies of COD, TN, TP were 93.2%, 71.2% and 95.7% respectively. The removed COD amount in the anaerobic reactor was about 85.9% of the total removed COD amount. The induced crystallization reactor played a key role in phosphorus removal. About 81.5% of the total removed phosphorus was taken up by crystallization. The proportion of the TN removal amount for the anaerobic reactor, aerobic reactor, anoxic reactor and post-aeration reactor were 31.7%, 11.4%, 54.9% and 2.0% respectively, and the anoxic reactor took the most. The post-aeration reactor undertook the important task of COD and ammonia nitrogen removal from the bypass sludge. Keywords: denitrifying phosphorus removal; two-sludge; crystallization; nitrogen and phosphorus removal 双污泥－诱导结晶工艺是将双污泥反硝化聚磷和诱导结晶有机结合起来的新型脱氮除（回收）磷工艺[1