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乳化剂对阳离子液聚合的影响及乳胶粒对棉纤维的吸附.pdf
Abstract
Cationic emulsionisusedinvarious
polymer fields,forinstance,sewagetreatment,
andbiomedicalfieldduetoits
papermakingindustry,textileindustry significant
andwith on
peculiarities,suchas,positivelycharged strongadsorptionabilitynegatively
surfaces.Inthis kindsofcationic cationic
charged article,six emulsifiers(traditional
surfactant,Geminicationic cationic
single-chain surfactant,polymerizablesingle-chain
Geminicationic usedandtwomethods
surfactant,polymerizablesurfactant)were
seededcationic
(semi—continuous emulsion cationicemulsion
polymerization,batch
takento variouskindsofcationicemulsion.Theeffectof
polymerization)wereprepare
theamountandthestructureoftheemulsifiersonnucleation
mechanism,the
conversionandreaction colloidal
polymerizationkinetics(instantaneous rate)and
features(stability,particlesize,PDI,zeta and
potential,surfacechargedensityglass
kindsofcationicemulsionswereusedto
changetemperature)Wasanalyzed.Several
the ofcationiclatex ontocotton
analyzeadsorptionproperties particles fibers(adsorption
rate,adsorptionisotherm).
The
resultsshowthatinthereactions、肮th surfactantslatex
non-polymerizableparticles
were
obtained nucleationmechanismandsmallerreaction
through
homogeneous rates,
greater size,smaller surface were
particle
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