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EG聚酯化反应动力学.pdf
第 66卷 第 11期 化 工 学 报 V_01．66NO．11
2015年 11月 CIESC Journal November2015
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MA／EG与TBPA／EG聚酯化反应动力学
孔明华，伍联营，徐显朕，胡仰栋
(中国海洋大学化学化工学院，山东 青岛 266100)
摘要：通过熔融缩聚反应对马来酸酐 ／乙二醇 (MA／EG)和四溴邻苯二 甲酸酐／乙二醇 (TBPAE／G)两个聚酯化反
应的动力学进行研究。考察了自催化条件下反应温度、原料配比对聚酯化反应速率的影响。在陈寿安模型的基础
上，对反应级数的不同组合进行了比较研究。结果表明：I-1模型和实验结果吻合 良好，且kh[H2O】为正值；温度
越高，醇酸配比越大，则聚合反应程度越大。
关键词：动力学模型；聚合；酯化；
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