磷氮硼阻燃剂处理对木聚糖热解产物的影响.pdfVIP

一五刁：-司卞讨耳∞弋令会刊 会议交流 磷氮硼阻燃剂处理对木聚糖热解产物的影响 隋淑娟王奉强 摘 要：采用Py—Gc—Ms联机分析技术，研究了磷一氮一硼系阻燃刺对紫椴木聚糖热解产物组成的影响。结果发现：紫椴未聚糖 热解时产生大量的co。等小分子化合物，经阻燃剂处理后，其热解焦油产物种类增多，初步鉴定了裂解产物中155种化合物的结 构。硼砂阻燃剂在木聚糖热解过程中可能主要起到物理覆盖和促进环化的阻燃作用，而硼酸可能促进了木聚糖进一步热解成小 分子化合物；有机磷阻燃剂促进环化的能力较强，更有利于碳氢化合物脱氢炭化过程的实现；GUP与硼酸复配为磷一氮一硼复合 型阻燃剂FgW后产生了明显的协同作用，抑制了焦油产量和某些化合物的产生，FTIg分析显示FgW可有效促进木聚糖在较低的温 度下成炭。 关键词：裂解一气相色谱一质谱木聚搪热解产物阻燃剂 InfluenceofPNBFire—RetardantstreatmentonThe Productsof Pyrolysis Xylan ShujuanSui，FengqiangWang Abstract：PV—GC—MSonline wasusedto effectsofthe fire analyticaltechnique study on Tilia resultsshowed numberof retardantsthe amurensisxylanpyrolysisproductcomposition．The that：alarge othersmallmolecular were when was CO，and compoundsproducedxylanpyrolyzing．Thepyrolysisproductspecies oftarwouldincreasewhen treatedwithfireretardant．153 inthe were xylan compoundsxy]anpyrolysisproducts identffied．Boraxfireretardantshave the rolesin and preliminarily may playedmajor physicalcoveragepromoting effectsinthe boticacid further intosmallmolecular cyclization xylanpyrolysisprocess．and may promotexylan fireretardantSbetter to realizationofthe compoundsl organicphosphorus having abilitypromotecyclization，the of andcarbonizationof wasmore processdehydrOgenation hydrocarbonsconducive,the boron fireretarclantFRW fromGUPandboricacidresultedinanobvious composite