高分子化学和物理博士课程2.ppt

Covalent Characterization 形态结构 形态结构 形态结构 形态结构 CNTs的结构缺陷 A: five- or seven-membered rings in the C framework, instead of the normal six-membered ring, lead to a bend in the tube; B: sp3-hybridized defects; R, —H and —OH C: C framework damaged by oxi- dative conditions, which leave a hole lined with —COOH groups; D: open the end of SWNTs, terminat-ed with —COOH groups. A. Hirsch, et al. Angew. Chem. Int. Ed. 2002, 41: 1853. 液晶性 如何解释 (1) The rigid rodlike molecule structure of CNTs (2)胆甾相高分子液晶的裂纹形织构 In general, the cholesteric liquid crystalline polymers exhibit the pa