zno微纳米结构薄膜的光响应润湿性-中国有色金属学报中文版英文版.pdfVIP

18 8 2008 8 Vol.18 No.8 The Chinese Journal of Nonferrous Metals Aug. 2008 1004-0609(2008)08-1517-05 ZnO ( 266033) ZnO ZnO (VUV)VUV 3 ZnO (CA 120˚)(CA~0˚) ZnO ZnO (CA 140˚) VUV ZnO ZnO ZnO ZnO TN 304.2; O 647.11 A Photoresponsive wettability of ZnO micro-nanostructure films LIU Chang-song, QIN You-pei, LI Zhi-wen, PU Pei-zhong, WANG Ling (School of Mechanical Engineering, Qingdao Technological University, Qingdao 266033, China) Abstract: Several ZnO micro-nano structures with different morphologies, such as rods, spheres and flowers, were prepared by means of low temperature liquid method tailored by hydrofluoric acid. Their vacuum-ultraviolet (VUV) photoresponsive wettabilities were focused. With VUV illumination time aging, the wettabilities of all ZnO micro-nanostructures change from high-hydrophobic (contact angle (CA) 120˚) to superhydrophilic (CA−0˚), and all of the water contact angles change with an uneven velocity: fast firstly, and then slowly. If the surfaces of ZnO micro-nanostructures are modified by n-octadecyltrimethoxysilane (ODS), i. e. the surfaces are coated by a self-assembly monolayer, their water contact angles increase (CA 140˚). Also, it takes more time to transmit from high-hydrophobic to superhydrophilic for ZnO surfaces under VUV illumination after they are modified by ODS. All of the results can be helpful to realize ZnO-based wettability-gradient surfaces. Key words: ZnO; thin film; wettability; micro-nanostructure; self-assembly monolayer; photoresponsive ZnO 10 [8−13] ZnO ZnO/(