阻燃TPEE非等温热氧降解动力学_朱新军.pdfVIP

35 1 ( ) Vol1 35, No. 1 2009 2 JOU RNAL OF DONGHUA UN IVERSIT Y( NAT URAL SCIENCE) Fe . 2009 : 1671-0444( 2009) 01-0017-06 * T PEE 1 1 1 2 朱新军, 彭治汉, 李文刚 , 刘森林 ( 1. , 201620; 2. , 200052) : 为了考察自制膦酸酯阻燃剂( DP-FR) 对热塑性聚酯弹性体(TPEE) 热性能的影响, 测得了阻燃TPEE( FR- TPEE) 共混材料空气气 下非等温热重(T G) 数据, 利用Kissinger 和Flynn-Wal-l Ozawa 两种动力学方法, 分别求得了 FR-TPEE 热氧降解反应活化能E a . 结果表明: DP-FR 对FR-T PEE 的初始分解温度最大降解温度影响不大, 对反应 活化能稍有影响, 阻燃材料仍具有很高的热稳定性. 研究结果还表明: DP-FR 提高了FR-TPEE 热氧降解的质量保留 率, 显示出较好的阻燃性. : 热塑性聚酯弹性体(TPEE) ; 阻燃剂; 动力学; 热氧降解; 反应活化能 + : O 631. 3 1 : A Non-isot hermal Kinet ics of Thermal Oxidat ive Degradat ion of Flame Retardant Thermoplast ic Polyester Elastomer 1 1 1 2 ZH U X in-j u n , P EN G Zhi-han , L I Wen-gang , L I U S en-li n ( 1. College of Material Science and Engineering, Donghua University, Shanghai 201620, China; 2. Sinote Investment Development Co Ltd, Shanghai 200052, China) Abstract: T he effects of phosphonate ester flame retardant ( DP-FR) on thermal sta ility of flame retardant thermoplastic polyester elastomer ( FR-TPEE) lends w ere studied. The kinetics of the thermal oxidative degradation of FR-T PEE lends w ere investigated y non-isothermal thermogravimetric analysis in air. Kissinger method and Flynn-Wall-Ozawa method had een used to determine the activation energies of FR- TPEE degradation, respectively. T he results show ed that DP-FR had a little influence on in