《Aliquat336萃取醋酸的平衡特性》.pdfVIP

53 9 V ol. 53 9 2002 9 Jou nal of Chemical I ndust y and Eng inee ing ( China) Septembe 2002 Aliquat 336 秦 炜 马志君 戴猷元 ( , 100084) Aliquat 336 , , , pH , Aliquat 336 , . : ; , Aliquat 336 , ; pH D , . A liquat 336 , K 1 , , K , 2 K 2 , , Aliquat 336 . A liquat 336 T Q 06- 332 A 0438- 1157 ( 2002) 09- 0957- 05 EXTRACTION EQUILIBRIUM OF ACETIC ACID WITH QUATERNARY AMINE Aliquat 336 QIN Wei, MA Zhi un and DAI Youyuan ( Dep artment of Chemical Engineering , Tsinghua University , Beij ing 100084, China) Abstract T he ext action of acet ic acid f om an aqueous solut ion int o solutions of quat e na y amine, Aliquat 336, in diff e ent diluent, n - oct anol, chlo of o m and ke osene, w as invest igat ed unde va ious pH, concent at ion of Aliquat 336 and solute. T he style of complex fo mation w as discussed, and a model desc ibing the equilib ium was p oposed. T he dist ibution coefficient, D, f itted t he simple addit ive p ope ty of Aliquat 336 and t he diluent . Diluent affected t he D appa ently; t he D in chlo ofo m a